139122-14-8

Basic information

• Product Name: 2H-Benzimidazol-2-one, octahydro-1,3-bis(2-methyl-1-oxo-3-phenylpropyl)-
• CAS NO: 139122-14-8
• Molecular Formula: C27H32N2O3
• Molecular Weight: 432.563
• Mol File: 139122-14-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2H-Benzimidazol-2-one, octahydro-1,3-bis(2-methyl-1-oxo-3-phenylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Benzimidazol-2-one, octahydro-1,3-bis(2-methyl-1-oxo-3-phenylpropyl)-(139122-14-8)
• EPA Substance Registry System: 2H-Benzimidazol-2-one, octahydro-1,3-bis(2-methyl-1-oxo-3-phenylpropyl)-(139122-14-8)

Safety Data

• Hazardous Substances Data: 139122-14-8(Hazardous Substances Data)

Upstream product

• 74-88-4 methyl iodide 
• 100-39-0 benzyl bromide 
• 139237-85-7 (R,R)-(-)-1,3-dipropionyl-trans-4,5-tetramethyleneimidazolidine-2-one 
• 1121-22-8 trans-1,2-Diaminocyclohexane 
• 30086-64-7 (3aS,7aS)-hexahydro-1H-benzo[d]imidazole-2(3H)-thione 
• 137618-00-9 1,3-di(3-phenyl-2-methylpropionyl)-trans-4,5-tetramethyleneimidazolidine-2-thione 

Relevant articles and documents

Bifunctional chiral auxiliaries 6: Alkylations of enolates derived from 1,3-diacylimidazolidine-2-thiones and 1,3-diacylimidazolidin-2-ones

Sodium and potassium enolates of 1,3-diacylimidazolidin-2-ones undergo clean alkylation reactions with reactive alkyl halides; the latter enolates reacting generally more stereoselectively due, it is proposed, to the lower temperature at which the reactio

Bifunctional chiral auxiliaries 2: The synthesis of 1,3-diacylimidazolidin-2-ones from 1,2-diamines

The title compounds are readily prepared in three steps via the corresponding 1,3-diacylimidazolidine-2-thiones. The final step involves the novel use of mercury (II) acetate for the conversion of thioureas to ureas.