1391997-82-2Relevant articles and documents
Synthesis of a sterically modulated pyridine-NHC palladium complex and its reactivity towards ethylene
Khlebnikov, Vsevolod,Meduri, Angelo,Mueller-Bunz, Helge,Milani, Barbara,Albrecht, Martin
, p. 1552 - 1555 (2012)
A new cationic pyridine-carbene palladium complex has been prepared that features a C,N-bidentate coordinating ligand with a shielded pyridine and a sterically less protected carbene moiety; evaluation of this complex in ethylene polymerization revealed competitive reductive elimination processes and provides guidelines for further catalyst design.