13920-89-3Relevant academic research and scientific papers
Solvent-free anti-markovnikov addition of thiols to alkenes using anhydrous cerium(III) chloride as catalyst
Silveira, Claudio C.,Mendes, Samuel R.,Líbero, Francieli M.
experimental part, p. 790 - 792 (2010/06/13)
The anti-Markovnikov addition of thiols to alkenes using CeCl3 as catalyst is described. The products were obtained in good to excellent yields. The reaction occurred under solvent-free conditions at room temperature.
N-Phenyltriazolinedione as an initiator in the radical addition of thiophenol to alkenes
Nicolaou, Georgia,Elemes, Yiannis
body text, p. 6324 - 6326 (2009/04/06)
N-Phenyltriazolinedione is found to be an efficient initiator in the radical (anti-Markovnikov) addition of thiophenol to 2-methyl-2-butene. A second, minor, product (an alcohol, from oxygen addition) was also obtained, and a possible mechanistic scheme is proposed.
ELECTROREDUCTIVE CLEAVAGE OF CARBON-SULPHUR BONDS IN DITHIOACETALS
Itter, Nicola Schultz-von,Steckhan, Eberhard
, p. 2475 - 2484 (2007/10/02)
The carbon-sulphur bond in aliphatic diphenyldithioacetals, α-carbonyldiphenyldithioacetals and α-carbonylketene dimethyldithioacetals can be cleaved cathodically on mercury (Hg) or glassy carbon (GC) electrodes.In the presence of tetrabutylammoniumhydrog
TITANIUM TETRACHLORIDE PROMOTED REDUCTION OF ALKENYL SULFIDES USING TRIETHYLSILANE AS A REDCING AGENT
Takeda, Takeshi,Tsuchida, Toshio,Fujiwara, Tooru
, p. 1219 - 1220 (2007/10/02)
Alkenyl sulfides were reduced to the corresponding alkyl sulfides with triethylsilane in the presence of titanium tetrachloride in good yields.The reduction proceeds via -phenylthio-alkyltitanium intermediate.
