17414-02-7

Basic information

• Product Name: 1,2-dimethylprop-1-enyl phenyl sulfide
• Synonyms: 1,2-dimethylprop-1-enyl phenyl sulfide
• CAS NO: 17414-02-7
• Molecular Weight: 178.298
• Mol File: 17414-02-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1,2-dimethylprop-1-enyl phenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-dimethylprop-1-enyl phenyl sulfide(17414-02-7)
• EPA Substance Registry System: 1,2-dimethylprop-1-enyl phenyl sulfide(17414-02-7)

Safety Data

• Hazardous Substances Data: 17414-02-7(Hazardous Substances Data)

Upstream product

• 13920-89-3 2-methyl-3-phenylthio-butane 
• 17414-14-1 (R,S)-3-methyl-2-(phenylsulfinyl)but-2-ene 
• 3017-70-7 2-bromo-3-methylbut-2-ene 
• 108-98-5 thiophenol 
• 598-25-4 Dimethylallene 
• 513-35-9 2-methyl-but-2-ene 
• 931-59-9 benzenesulfenyl chloride 
• 563-80-4 3-methyl-butan-2-one 

Downstream Products

• 115993-71-0 2,3-Dimethyl-2-phenylsulfanyl-butyronitrile 
• 127632-15-9 3-Benzenesulfinyl-2-methyl-but-3-en-2-ol 
• 137041-37-3 1-<2-(dimethylphenylsilyl)-1,1-dimethyl-2-propenyl>-4-methyl-1,2,4-triazolidine-3,5-dione 
• 85895-10-9 2-methyl-3-(phenylthio)-2-pentene 
• 85895-29-0 24-(phenylsulfinyl)-22-(phenylsulfonyl)spiro<4,24-cholestadiene-3,2'-(1',3'-dithiacyclohexane)> 
• 85895-31-4 26-hydroxy-22-(phenylsulfonyl)spiro<4,24-cholestadiene-3,2'-(1',3'-dithiacyclohexane)> 
• 85894-94-6 1,1,-bis(phenylsulfonyl)-4-methyl-3-(phenylthio)-3-pentene 
• 85895-21-2 2-carbethoxy-2-(2-(phenylsulfinyl)-3-methyl-2-butenyl)cyclopentanone 
• 85895-38-1 1-methyl-4-(6-methyl-5-(phenylsulfinyl)-1,5-heptadien-2-yl)cyclohexene 
• 85895-24-5 1-methyl-4-(6-methyl-5-(phenylthio)-1,5-heptadien-2-yl)cyclohexene 
• 85895-20-1 1-bromo-2-(phenylsulfinyl)-3-methyl-2-butene 
• 18681-09-9 (+/-)-lanceol 
• 1886-64-2 3,3-dimethylbut-1-en-2-yl phenyl sulfide 
• 174316-02-0 3-Benzenesulfinyl-2-methyl-but-3-en-2-yl-hydroperoxide 

Relevant articles and documents

General Synthesis of Alkenyl Sulfides by Palladium-Catalyzed Thioetherification of Alkenyl Halides and Tosylates

The cross-coupling reaction of alkenyl bromides with thiols catalyzed by palladium complexes derived from inexpensive dppf ligand is reported. These reactions occur under low catalyst loading and in high yields and display wide scope, including the coupling of bulky thiols and trisubstituted bromoolefins, and functional group tolerance. In addition, the thioetherification of less reactive chloroalkenes and, for the first time, alkenyl tosylates was accomplished using a catalyst generated from CyPFtBu alkylbisphosphine ligand.

Highly regioselective addition of benzenethiol to allenes catalyzed by palladium acetate

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THE REACTION OF ALKYL PHENYL SULPHIDES WITH MANGANESE DIOXIDE AND ACETYL CHLORIDE

In a one-pot reaction, manganese dioxide in stoichiometric amounts and acetyl chloride transform alkyl phenyl sulphides into the corresponding 1-alkenyl phenyl sulphides; these latter products can be undergo chlorination of the double bond promoted by the