1392008-34-2

Upstream product

• 95-87-4 2,5-Dimethylphenol 
• 629-03-8 1 ,6-dibromohexane 
• 25812-52-6 2-(6-bromohexyloxy)-1,4-dimethylbenzene 
• 39630-68-7 diethyl 5-hydroxyisophthalate 

Downstream Products

• 1392008-38-6 5,5'-(5-(6-(2,5-dimethylphenoxy)hexyloxy)-1,3-phenylene)-bis(2-(4-(n-dodecyloxy)phenyl)-1,3,4-oxadiazole) 
• 1392008-39-7 1,3-bis[2-(4-(n-dodecyloxy)phenyl)-1,3,4-oxidiazole-5-yl]-5-[3-(2,5-dibromomethyl)phenoxyhexyloxy]benzene 

Relevant academic research and scientific papers

Oxadiazole containing poly(p-phenylenevinylene)s: Synthesis and characterization

A series of poly(p-phenylenevinylene) based polymers (MEH-OXD-PPVs) functionalized with Y-shaped double 1,3,4-oxadiazole-containing side chains were synthesized through a modified Gilch reaction. They are all soluble in common organic solvents such as chloroform, tetrahydronfuran and 1,1,2,2- tetrachloroethane. The chemical structures of MEH-OXD-PPVs were determined by 1H NMR, GPC and elemental analysis. Thermogravimetric analysis shows that they have good thermal stability with the decomposition temperature ranging from 312°C to 326°C. The absorption and fluorescence emission maxima of the polymers exhibit an appreciable blue-shift with the increase of oxadiazole-containing moieties. Electrochemical investigation shows that the HOMO energy levels of the polymers vary regularly with the change of content of oxadiazole-containing moieties. Additionally, by introducing more OXD-PV unit during copolymerization, the PL quantum efficiencies of the polymers are significantly enhanced compared to that of MEH-PPV. The successful manipulation of optical and electronic properties of the MEH-OXD-PPVs indicates an effective concept for developing PPV-based functional materials with tunable optoelectronic properties by changing the amount of electron-withdrawing oxadiazole-containing moieties.