1392011-57-2Relevant academic research and scientific papers
The role of cyclobutenes in gold(I)-catalysed skeletal rearrangement of 1,6-enynes
Escribano-Cuesta, Ana,Perez-Galan, Patricia,Herrero-Gomez, Elena,Sekine, Masaki,Braga, Ataualpa A. C.,Maseras, Feliu,Echavarren, Antonio M.
supporting information; experimental part, p. 6105 - 6111 (2012/09/05)
1,6-Enynes with electron-donating substituents at the alkyne undergo gold(i)-catalysed single cleavage skeletal rearrangement, whereas substrates with electron-withdrawing substituents evolve selectively to double cleavage rearrangement. Theoretical calcu
