1392231-55-8

Basic information

• Product Name: C₁₄H₁₀N₆
• CAS NO: 1392231-55-8
• Molecular Weight: 262.274
• Mol File: 1392231-55-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₀N₆(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₀N₆(1392231-55-8)
• EPA Substance Registry System: C₁₄H₁₀N₆(1392231-55-8)

Safety Data

• Hazardous Substances Data: 1392231-55-8(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 
• 2294-47-5 1,4-diazidobenzene 

Relevant articles and documents

Di-mesoionic carbene-bridged complexes of Rh2, Ir2, and RhIr: A stepwise metalation strategy for the synthesis of di-MIC-bridged mixed-metal systems

A meta-substituted benzene-bridged ditriazolium salt has been prepared using copper-catalyzed azide-alkyne cycloaddition (CuAAC or click chemistry) and methylation protocols. Metalation of this dicationic species by basic-ligand-containing [Rh(μ-OMe)(COD)]2 and [Ir(μ-OMe)(COD)] 2 precursors provides homobimetallic complexes of Rh and Ir bridged by a 1,2,3-triazol-5-ylidene-type di-mesoionic carbene (di-MIC) via an internal-base strategy. By using only 1/2 equiv of the internal-base precursor, mononuclear MIC-anchored/pendent- triazolium intermediates have been isolated, in which only one end of the ditriazolium salt has been deprotonated and attached to Rh or Ir. Reaction of these pendent intermediates with another 1/2 equiv of an internal-base precursor affords either the aforementioned homobimetallic products or an analogous di-MIC-bridged, mixed-metal Ir/Rh complex.