13927-77-0Relevant articles and documents
Structural organization of nickel(II), zinc(II), and copper(II) complexes with diisobutyldithiocarbamate: EPR, 13C and 15N CP/MAS NMR, and X-ray diffraction studies
Ivanov,Korneeva,Gerasimenko,Forsling
, p. 695 - 707 (2008/10/09)
The structures and spectroscopic properties of nickel(II), zinc(II), and copper(II) complexes with dibutyl- and diisobutyldithiocarbamate were studied by EPR and 13C and 15N CP/MAS NMR spectroscopy and X-ray diffraction analysis. According to the EPR data, copper(II) forms mononuclear [63/65Cu{S2CNR2}2] and heterobinuclear complexes [63/65CuZn{S2CNR 2}4] under magnetic dilution conditions. The isomeric forms of nickel(II) and zinc(II) diisobutyldithiocarbamates were detected by 13C and 15N NMR spectroscopy. The crystalline zinc(II) diisobutyldithiocarbamate was found to have a unique structural organization with alternating mononuclear [Zn{S2CN(i-C4H 9)2}2] and binuclear molecular forms [Zn 2{ S2CN(i-C4H9)2} 4] in the 1 : 1 ratio.