139284-73-4Relevant academic research and scientific papers
Stereoselective syntheses of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone via alkoxyallylboration and ring-closing metathesis
Ramachandran, P. Veeraraghavan,Chandra, J. Subash,Reddy, M. Venkat Ram
, p. 7547 - 7550 (2007/10/03)
A convenient synthesis of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways.
Enantioselective allyltitanation of aldehydes with cyclopentadienylialkoxyallylitanium complexes
Hafner, Andreas,Duthaler, Rudolf O.,Marti, Roger,Rihs, Grety,Rothe-Streit, Petra,Schwarzenbach, Franz
, p. 2321 - 2336 (2007/10/02)
The preparation, analysis, and reactions of novel, highly stereoselective cyclopentadienyldialkoxyallyltitanium reagents, available in both enamiomeric forms, are described. Chiral monochlorotitanates are readily prepared from CpTiCl3 or Cp*TiC
