1393083-66-3

Basic information

• Product Name: 6-O-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-α-D-glucopyranose
• Synonyms: 6-O-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-α-D-glucopyranose
• CAS NO: 1393083-66-3
• Molecular Weight: 508.635
• Mol File: 1393083-66-3.mol

Chemical Properties

• CAS DataBase Reference: 6-O-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-α-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-α-D-glucopyranose(1393083-66-3)
• EPA Substance Registry System: 6-O-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-α-D-glucopyranose(1393083-66-3)

Safety Data

• Hazardous Substances Data: 1393083-66-3(Hazardous Substances Data)

Upstream product

• 1393083-70-9 4'-monomethoxytrityl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-1-deoxy-α-D-glucopyranoside 
• 1393083-69-6 4'-monomethoxytrityl 2,3,4-tri-O-benzyl-1-thio-1-deoxy-α-D-glucopyranoside 
• 130539-62-7 6-O-acetyl-1-S-acetyl-2,3,4-tri-O-benzyl-1-deoxy-1-thio-α-D-glucopyranose 

Downstream Products

• 1452840-28-6 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-glucopyranosyl-(1,1’)-dithio-2-acetamido-2-deoxy-3,4,6-tri-O-acetyl-1-thio-β-D-glucopyranoside 
• 1452840-27-5 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-glucopyranosyl-(1,1’)-dithio-2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 1393083-67-4 6-O-acetyl-2,3,4,2′,3′,4′,6′-hepta-O-benzyl-1-thio-α,α-D-trehalose 

Relevant articles and documents

A facile and highly stereoselective synthesis of 1-thiotrehalose

A facile and highly stereoselective synthesis of 1-thiotrehalose, that is, α,α-S-linked trehalose, is described. Glycosylation of configurationally pure α-glucosyl thiol 5 with glucosyl trichloroacetimidate 6 or glucosyl thioimidate 9 followed by deprotection afforded 1-thiotrehalose in excellent α-stereoselectivity and high yield. A different synthetic route to the key building block, α-glucosyl thiol 5, was also investigated in this report.