1393357-52-2Relevant academic research and scientific papers
Synthesis of a stable 1,2-bis(ferrocenyl)diphosphene
Sasamori, Takahiro,Sakagami, Michiyasu,Niwa, Masatoshi,Sakai, Heisuke,Furukawa, Yukio,Tokitoh, Norihiro
, p. 8562 - 8564 (2012/08/29)
The synthesis and characterization of a stable 1,2-bis(ferrocenyl) diphosphene, wherein a PP π-bond connects two ferrocenyl units will be reported. This represents an unprecedented example for a d-π electron system containing a heavier pnictogen π-spacer group. Stabilization of the highly reactive PP π-bond was achieved by steric protection using two bulky ferrocenyl moieties.
