1393475-23-4Relevant academic research and scientific papers
An asymmetric hydroformylation catalyst that delivers branched aldehydes from alkyl alkenes
Noonan, Gary M.,Fuentes, Jose A.,Cobley, Christopher J.,Clarke, Matthew L.
supporting information; experimental part, p. 2477 - 2480 (2012/04/18)
Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde. Copyright
LIGANDS FOR SELECTIVE ASYMMETRIC HYDROFORMYLATION
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Page/Page column 21-22, (2012/02/13)
In an aspect, the invention provides compounds of the formula 4: wherein the constituent variables are defined herein.
