1393484-89-3Relevant academic research and scientific papers
Cobalt (II) and copper (I) complexes of rigid bidentate [N-(2, 6-diisopropyl-phenyl)imino]acenapthenone ligand: Synthesis and structural studies
Anga, Srinivas,Paul, Mitali,Naktode, Kishor,Kottalanka, Ravi K.,Panda, Tarun K.
, p. 1311 - 1315 (2012)
The cobalt(II) complex [CoCl2(2, 6-iPrC6H 3-BIAO)]2 (1) of rigid unsymmetrical imine, carbonyl mixed ligand [N-(2, 6-diisopropylphenyl)-imino]acenapthenone] (2, 6-iPrC 6H3-BIAO) (L1) can be achieved by the reaction of CoCl2 and neutral [N-(2, 6-diisopropylphenyl)-imino]acenapthenone] ligand. When ligand L1 reacted with CuCl in dichloromethane solution, only nitrogen coordinated copper complex [CuCl(2, 6-iPrC6H 3-BIAO)] (2) was obtained. In the solid-state structure, compound 1 is dimeric through the chelating two μ2 chlorine atoms and each cobalt atom adopts either a distorted trigonal bipyramidal or a distorted square pyramidal arrangement. In contrast, the molecular structure of compound 2 reveals that copper is coordinated by imino nitrogen and adopts a linear arrangement around the central metal atom. The crystal structure of the rigid bidentate mixed nitrogen and oxygen ligand (2, 6-iPrC6H 3-BIAO) (L1) is also reported. Copyright
