1393604-82-4Relevant academic research and scientific papers
Palladium-catalyzed oxidative acyloxylation/carbocyclization of allenynes
Deng, Youqian,Baeckvall, Jan-E.
, p. 3217 - 3221 (2013/04/24)
New bonds: The title reaction provides access to synthetically useful acyloxylated vinylallenes where a new C-C bond, a new C-O bond, and a new allene structure are formed. Furthermore, an aerobic version of this transformation was realized using catalytic amounts of p-benzoquinone (BQ) together with catalytic amounts of cobalt salophen.
Topological study of mechanistic diversity in conjugated fatty acid biosynthesis
Bhar, Palash,Reed, Darwin W.,Covello, Patrick S.,Buist, Peter H.
supporting information; experimental part, p. 6686 - 6690 (2012/08/27)
Variations on an oxidative theme: The precision with which FAD2-type desaturases carry out C-H activation reactions on flexible lipidic substrates is astonishing. The conformational space available within the active site of these enzymes has been explored using deuterium-labeled substrates, and evidence for a novel quasi-eclipsed conformer has been uncovered. The scheme shows some prototypical substrate conformations. Copyright
