139366-61-3Relevant academic research and scientific papers
TRITHIADIAZEPYNE
Plater, M. J.,Rees, C. W.
, p. 261 - 288 (2007/10/02)
Amino derivatives of the trithiadiazepine ring system are described for the first time.They are available by nucleophilic aromatic substitution under remarkably mild conditions, though only via the hetaryne intermediate.Firm evidence is presented for the involvement of this relatively stable aryne, and some new rearrangements accompanying or following its interception by dienes and dipoles are described.
