139371-75-8Relevant academic research and scientific papers
From disubstituted acetylenes to trisubstituted olefins. An application
Benechie, Michel,Skrydstrup, Troels,Khuong-Huu, Francoise
, p. 7535 - 7538 (1991)
The transformation of disubstituted acetylenes to trisubstituted olefins was studied in order to obtain precursors of the north-eastern part of maytansine. Depending on the starting material, a trans or a cis stannylation reaction could lead to the olefin of the desired stereochemistry.
