From disubstituted acetylenes to trisubstituted olefins. An application

DOI: 10.1016/0040-4039(91)80527-D

Source and publish data:

Tetrahedron Letters p. 7535 - 7538 (1991)

Update date:2022-07-29

Topics:

Authors:

Benechie, Michel

Skrydstrup, Troels

Khuong-Huu, Francoise

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Article abstract of DOI:10.1016/0040-4039(91)80527-D

The transformation of disubstituted acetylenes to trisubstituted olefins was studied in order to obtain precursors of the north-eastern part of maytansine. Depending on the starting material, a trans or a cis stannylation reaction could lead to the olefin of the desired stereochemistry.

Full text of DOI:10.1016/0040-4039(91)80527-D

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