From disubstituted acetylenes to trisubstituted olefins. An application

DOI: 10.1016/0040-4039(91)80527-D

Source and publish data:

Tetrahedron Letters p. 7535 - 7538 (1991)

Update date:2022-07-29

Topics:

Authors:

Benechie, Michel

Skrydstrup, Troels

Khuong-Huu, Francoise

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80527-D

The transformation of disubstituted acetylenes to trisubstituted olefins was studied in order to obtain precursors of the north-eastern part of maytansine. Depending on the starting material, a trans or a cis stannylation reaction could lead to the olefin of the desired stereochemistry.

Full text of DOI:10.1016/0040-4039(91)80527-D

Products guided by the article

Product name:((E)-(1R,2S)-1-Benzyloxymethyl-4-iodo-2-methyl-pent-3-enyloxy)-tert-butyl-dimethyl-silane

Cas No:139371-75-8

R&D Labs maybe for 139371-75-8

Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Suzhou Kangrun Pharmaceutical, Inc

Contact:86-512-63912376，63913329

Address:Building 2, No. 2358 ,Chang'an Rd, Wujiang Economic Development Zone Pioneering park, china

Relevant to this article

Stoichiometric reactions of enamines derived from diphenylprolinol silyl ethers with nitro olefins and lessons for the corresponding organocatalytic conversions - A survey

Doi:10.1002/hlca.201300079
(2013)
Copper(II)-Catalysed Aerobic Oxidative Coupling of Arylamines with Hexafluoroisopropanol: An Alternative Methodology for Constructing Fluorinated Compounds

Doi:10.1002/adsc.202001048
(2021)
Aerobic cross-dehydrogenative coupling of terminal alkynes and tertiary amines by a combined catalyst of Zn²⁺ and OMS-2

Doi:10.1039/c4ra05105j
(2014)
Novel 2-methoxyacylhydrazones as potent, selective PDE10A inhibitors with activity in animal models of schizophrenia

Doi:10.1016/j.bmcl.2012.07.007
(2012)
Identification of aminopyridazine-derived antineuroinflammatory agents effective in an Alzheimer's mouse model

Doi:10.1021/ml3001769
(2012)
Enzymatic single-step formation of laureat in and its key intermediate, prelaureatin, from (3Z, 6S, 7S)-laurediol

Doi:10.1016/0040-4039(92)88128-R
(1992)

Article Doi