13938-22-2

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 103-79-7 1-phenyl-acetone 
• 696-62-8 para-iodoanisole 

Downstream Products

• 161260-23-7 (E)-4-(p-Methoxyphenyl)-3-phenylbuten-2-one tosylhydrazone 
• 13938-23-3 1-(4-Methoxyphenyl)-2-phenyl-3-oxo-4-acetoxy-but-1-en 
• 1386421-64-2 C₁₈H₁₉N₃OS 
• 1386421-54-0 C₂₃H₂₁N₃O₃S 
• 53448-91-2 3-(4-methoxyphenyl)-2,4,5-triphenylfuran 
• 6968-77-0 3-(4-methoxyphenyl)-2-phenylacrylic acid 
• 161260-31-7 3-Isobutenyl-1-(p-methoxyphenyl)-3-methyl-2-phenylcyclopropene 
• 161260-20-4 1-(p-Methoxyphenyl)-3-methyl-2-phenylcyclopropene 

Relevant academic research and scientific papers

Acid-catalyzed synthesis of α,β-disubstituted conjugated enones by a Meyer-Schuster-type rearrangement in allenols

A novel, direct and simple methodology to gain access to α,β-disubstituted conjugated enones from α-allenols in a sustainable metal catalysis context, considering the inexpensiveness and environmentally friendliness of iron(III) species and protons, has b

Synthesis and antimicrobial evaluation of some pyrazole derivatives

Reaction of a series of (E)-3-phenyl-4-(p-substituted phenyl)-3-buten-2- ones with p-sulfamylphenyl hydrazine in glacial acetic acid gave the corresponding hydrazones, subsequent treatment of which with 30% HCl afforded pyrazole-1-sulphonamides. On the ot

Iridium-catalyzed asymmetric hydrogenation of α-substituted α,β-unsaturated acyclic ketones: Enantioselective total synthesis of (-)-mesembrine

A highly efficient asymmetric hydrogenation of α-substituted α,β-unsaturated acyclic ketones catalyzed by chiral spiro iridium complexes for the preparation of chiral 2-substituted allylic alcohols has been developed (ee up to 99.7%). This method provides a concise route to (-)-mesembrine (34% yield, 12 steps).

Regio- and stereochemical aspects of the palladium-catalyzed desilylation-arylation of substituted vinylsilanes

The palladium-catalyzed desilylation-arylation of substituted vinylsilanes by p-iodoanisole in the presence of bidentate phosphine ligands is described. Apart from enhancing the rate of the reaction considerably, heteroatom-based functional groups in the vinylsilane moiety have a profound influence on the regiochemistry. A catalytic cycle for the chelation-controlled desilylation-arylation reaction involving five- and six-membered chelate rings is proposed.

Singlet Photochemistry of Vinylcyclopropenes. Regioselectivity and Mechanism: Mechanistic and Exploratory Organic Photochemistry

A study of the direct photochemistry of 1-anisyl-2-phenyl-3-methyl-3-isobutenylcyclopropene (5) was pursued with the objective of elucidating the reaction regioselectivity and casting light on alternative reaction mechanisms for this reaction known to aff