1393879-08-7Relevant academic research and scientific papers
Catalytic monosilylation of 1,2-diols
Takeichi, Tsubasa,Kuriyama, Masami,Onomura, Osamu
, p. 6646 - 6648 (2011)
The selective monosilylation of 1,2-diols catalyzed by dimethyltin dichloride was successfully developed. This procedure was applied to various 1,2-diols, giving monosilylated products in good to excellent yields with high chemoselectivity.
A method of manufacturing a silyl ether compd. hydroxyacid
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Paragraph 0078; 0085, (2016/12/22)
PROBLEM TO BE SOLVED: To provide a method for obtaining a hydroxysilyl ether compound by turning one hydroxy group out of two hydroxy groups of a diol compound into a silyl ether. SOLUTION: In the method for producing a hydroxysilyl ether compound in good yield, the objective compound is prepared by reacting, in an organic solvent, the diol compound (e.g., cis-1,2-cyclooctanediol (cyclic 1,2-diol compound)) selected from a cyclic 1,2-diol compound, a chain 1,2-diol compound and chain 1,3-diol compound with an organic silicon halide compound in the presence of a Lewis acid catalyst and an organic base. COPYRIGHT: (C)2012,JPOandINPIT
