139404-87-8Relevant academic research and scientific papers
Enantioselective Synthesis of Homoallylic Amines by Addition of Allylmetal Reagents to Imines Derived from (S)-Valine Esters
Basile, Tiziana,Bocoum, Allaye,Savoia, Diego,Umani-Ronchi, Achille
, p. 7766 - 7773 (2007/10/02)
Grignard and Barbier procedures have been applied to the addition of allylmethal (Zn, Cu, Pb, Bi, Al, In) species to imines derived from (S)-valine esters, principally the methyl ester.The Zn-mediated, CeCl3- or SnCl2-catalyzed "Barbier" reactions of the
Asymmetric aza Diels-Alder reactions of amino acid ester imines with Brassard's diene
Waldmann,Braun,Drager
, p. 1231 - 1246 (2007/10/02)
Imines 1 obtained from aromatic, aliphatic or functionalized aldehydes and valine tert-butyl ester undergo Lewis acid catalyzed hetero Diels-Alder reactions with Brassard's diene 2. The cycloadducts are formed in good to high yields and with diastereomer
