139416-17-4Relevant academic research and scientific papers
P-chiral thioxophosphoranesulfenyl chlorides RR'P(S)SCl. A unique stereochemical probe to study nucleophilic displacement at a dicoordinate sulfur center
Luczak, Lech,Lopusinski, Andrzej,Michalski, Jan
, p. 9731 - 9746 (1998)
A stereospecific synthesis of P-chiral sulfenyl chlorides 6a,b has been developed from P-chiral sulfenylamide 9a,b,c by a novel procedure employing 2Me3SiCl + 2EtOH as the reagent of choice. The sulfenylamides 9a,b,c were prepared either by ste
P-Chiral Thioxaphosphoranesulphenyl Chlorides 1P(S)SCl>. Unique Stereochemical Probe for the Nucleophilic Displacements at the Dico-ordinate Sulphur
Lopusinski, Andrzej,Luczak, Lech,Michalski, Jan
, p. 1694 - 1695 (2007/10/02)
P-Chiral thioxaphosphoranesulphenyl chlorides 1P(S)SCl> (R=L-menthoxy, R1=EtO) are synthesized in high yield and with optical purity, they are shown to undergo nucleophilic attack at the dico-ordinate sulphur centre by a synchrono
