P-chiral thioxophosphoranesulfenyl chlorides RR'P(S)SCl. A unique stereochemical probe to study nucleophilic displacement at a dicoordinate sulfur center

DOI: 10.1016/S0040-4020(98)00529-8

Source and publish data:

Tetrahedron p. 9731 - 9746 (1998)

Update date:2022-07-29

Topics:

Authors:

Luczak, Lech

Lopusinski, Andrzej

Michalski, Jan

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Article abstract of DOI:10.1016/S0040-4020(98)00529-8

A stereospecific synthesis of P-chiral sulfenyl chlorides 6a,b has been developed from P-chiral sulfenylamide 9a,b,c by a novel procedure employing 2Me₃SiCl + 2EtOH as the reagent of choice. The sulfenylamides 9a,b,c were prepared either by ste

Full text of DOI:10.1016/S0040-4020(98)00529-8

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