1394226-64-2

Upstream product

• 1394226-61-9 (R)-5-(2-hydroxypent-4-en-1-yl)-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one 
• 1021299-73-9 2-(7-methoxy-2,2-dimethyl-4-oxo-4H-benzo[d][1,3]dioxin-5-yl)acetaldehyde 
• 1021299-51-3 5-allyl-7-methoxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one 
• 532394-17-5 7-methoxy-2,2-dimethyl-5-(trifluoromethylsulfonyloxy)benzo[1,3]dioxin-4-one 
• 1394226-63-1 (S)-3-(benzyloxy)-4-(7-methoxy-2,2-dimethyl-4-oxo-4Hbenzo[d][1,3]dioxin-5-yl)butanal 
• 24850-33-7 allyltributylstanane 
• 882980-43-0 2-benzyloxy-1-methylpyridinium triflate 
• 532394-23-3 5-hydroxy-7-methoxy-2,2-dimethyl-benzo[1,3]dioxin-4-one 
• 137571-73-4 5,7-dihydroxy-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one 

Relevant academic research and scientific papers

Total synthesis of 7-deoxy-6-o-methylfusarentin featuring a chelation-controlled 1,3-reetz-keck-type allylation

The total synthesis of 7-deoxy-6-O-methylfusarentin (1) and a formal synthesis of 7-deoxy-6,8-O-dimethylfusarentin (2) has been successfully achieved in 10 steps. The described tactic underscores a diastereoselective strategy which incorporates a single acyclic reaction based on the initial stereocenter by means of a 1,3-chelation-controlled Reetz-Keck-type allylation.