1394231-60-7

Basic information

• Product Name: 1,8-bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene
• Synonyms: 1,8-bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene
• CAS NO: 1394231-60-7
• Molecular Weight: 320.434
• Mol File: 1394231-60-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,8-bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,8-bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene(1394231-60-7)
• EPA Substance Registry System: 1,8-bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene(1394231-60-7)

Safety Data

• Hazardous Substances Data: 1394231-60-7(Hazardous Substances Data)

Upstream product

• 5720-07-0 4-methoxyphenylboronic acid 
• 206761-13-9 {1,8-bis(dimethylamino)naphthalene-2-yl} bromide 

Relevant articles and documents

1,8-Bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene: An electrospray-active analogue for η6-coordinating ligands

1,8-Bis(dimethylamino)-2-(4-methoxyphenyl)naphthalene (1) was synthesized for use as an η6-coordinating ligand with a chargeable tag for ESI-MS analysis. The pKa of the proton sponge moiety was essentially unaffected by addition of the anisole group (pKa = 18.2 ± 0.7 at 297 K in CD3CN). Cr(η6-1)(CO)3 (2) was prepared to demonstrate the utility of (1) as an ESI tag and 2 was easily visible by ESI(+)-MS. A single crystal structure of the complex showed η6-binding of the ligand as expected with the charged moiety being far removed from the metal centre. The gas-phase reactivity of 2 was found to match that of the analogous uncharged chromium carbonyl complex Cr(C 6H5OCH3)(CO)3 indicating that 1 has potential as a chargeable tag for the study of organometallic complexes and their reactions by ESI-MS.