1394231-71-0Relevant academic research and scientific papers
A cyclic diaminocarbene with a pyramidalized nitrogen atom: A stable N-heterocyclic carbene with enhanced electrophilicity
Martin, David,Lassauque, Nicolas,Donnadieu, Bruno,Bertrand, Guy
, p. 6172 - 6175 (2012/08/14)
An anti-Bredt NHC! Placing one of the adjacent nitrogen atoms of an NHC in the bridgehead position of a bicyclic scaffold prevents the donation of its lone pair. Thus, the π-electron-accepting properties of the carbene center are enhanced, while the strong -electron-donating properties of classical NHCs are retained. Copyright
