139462-25-2

Upstream product

• 137238-71-2 (4R)-3-[2-(Phenylmethoxy)acetyl]-4-(phenylmethyl)oxazolidin-2-one 
• 78-84-2 isobutyraldehyde 

Downstream Products

• 905307-73-5 (2R,3R)-2-benzyloxy-N,4-dimethyl-3-hydroxy-N-methoxy-pentanamide 
• 139561-11-8 (2S,3R)-2-benzyloxy-3-hydroxy-4-methyl-pentan-1-ol 
• 905307-81-5 (2S,4S,5R)-5-hydroxy-2-(4-methoxyphenyl)-4-(methylethyl)-1,3-dioxane 
• 905307-77-9 (2R,3R)-2-benzyloxy-3-tert-butyldimethylsilyloxy-4-methyl-pentanal 
• 905307-80-4 (2R,3R)-2-benzyloxy-3-(4-methoxybenzyl)-4-methyl-pentanal 
• 905307-84-8 (2R,3R)-2-tert-butyldimethylsilyloxy-3-(4-methoxybenzyl)-4-methyl-pentanal 
• 905307-79-1 (2S,3R)-2-benzyloxy-3-(4-methoxybenzyl)-4-methyl-pentan-1-ol 
• 905307-83-7 (2S,3R)-2-tert-butyldimethylsilyloxy-3-(4-methoxybenzyl)-4-methyl-pentan-1-ol 
• 905307-75-7 (2R,3R)-2-benzyloxy-3-tert-butyldimethylsilyloxy-N,4-dimethyl-N-methoxy-pentanamide 
• 905308-67-0 (4R,5S,6R)-5-benzyloxy-4-hydroxy-6-[(4-methoxybenzyl)oxy]-7-methyl-octan-2-one 

Relevant academic research and scientific papers

Asymmetric induction in methyl ketone aldol additions to α-alkoxy and α,β-bisalkoxy aldehydes: A model for acyclic stereocontrol

A systematic study of methyl ketone aldol additions under nonchelating conditions with α-alkoxy and α,β-bisalkoxy aldehydes is described. Additions to aldehydes containing a single α-alkoxy stereocenter generally provide the product diastereomers in accor

Asymmetric Synthesis of Calyculin A. 2. The C26-C37 γ-Amino Acid Fragments

New chiral imide enolate alkylation, aldol, and Michael addition bond constructions have been employed in the asymmetric synthesis of the C26-C37 portion of calyculin A.