139495-13-9Relevant academic research and scientific papers
Intramolecular hydride migration from formyl to carbonyl and nitrene ligands
Luan,Brookhart,Templeton
, p. 1433 - 1435 (1992)
Reaction of [Tp′W(CO)2(NPh)][PF6] [Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate] with lithium borohydride at -40°C generates Tp′W(CO)(NPh)(CHO) (1), which undergoes hydride migration from carbon to nitrogen (at -70°C, kobs
