Intramolecular hydride migration from formyl to carbonyl and nitrene ligands

DOI: 10.1021/om00040a003

Source and publish data:

Organometallics p. 1433 - 1435 (1992)

Update date:2022-08-03

Topics:

Authors:

Luan Luan

Brookhart

Templeton

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00040a003

Reaction of [Tp′W(CO)₂(NPh)][PF₆] [Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate] with lithium borohydride at -40°C generates Tp′W(CO)(NPh)(CHO) (1), which undergoes hydride migration from carbon to nitrogen (at -70°C, k_obs

Full text of DOI:10.1021/om00040a003

Products guided by the article

Product name:{((C₃N₂H(CH₃)2)3BH)W(CO)(N(C₆H₅))(COC₆H₅)}

Cas No:139495-13-9

R&D Labs maybe for 139495-13-9

Beijing Cooperate Pharmaceutical Co.,Ltd

website:http://www.cooperate-pharm.com/

Contact:86-01060279497

Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Hangzhou Zhenghan Biological Technology Co., Ltd.

Contact:86-571-88781753

Address:liangzhu yuhang hangzhou city
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Wuxi Morality Chemical Co., Ltd(expird)

Contact:

Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China
Shanghai Yuanding Chem. Sci. & Tech. Co., Ltd.

website:http://www.shydtec.com

Contact:86-21-57721279

Address:Science and Technology Park, Songjiang District, Shanghai, China

Relevant to this article

Photochemistry of Polyhaloarenes. 12. The Photochemistry of Pentachlorobenzene in Micellar Media

Doi:10.1021/jo00036a017
(1992)
A general and regioselective synthesis of 5-trifluoromethyl-pyrazoles

Doi:10.1021/ol3021918
(2012)
Asymmetric synthesis of diethyl α-amino-α-alkyl-phosphonates by alkylation of the chiral Schiff base derived from (+)-ketopinic acid and diethylaminomethyl phosphonate

Doi:10.1080/00397919208021082
(1992)
A novel polythiophene derivative as a sensitive colorimetric and fluorescent sensor for anionic surfactants in water

Doi:10.1039/c2nj40460e
(2012)
Dimetal complexes of a bibrachial 2+2 thiolate-based macrocycle

Doi:10.1080/10610278.2012.701302
(2012)
Adenosine analogs as inhibitors of tyrosyl-tRNA synthetase: Design, synthesis and antibacterial evaluation

Doi:10.1016/j.bmc.2015.09.018
(2015)

Article Doi