Intramolecular hydride migration from formyl to carbonyl and nitrene ligands

DOI: 10.1021/om00040a003

Source and publish data:

Organometallics p. 1433 - 1435 (1992)

Update date:2022-08-03

Topics:

Authors:

Luan Luan

Brookhart

Templeton

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Article abstract of DOI:10.1021/om00040a003

Reaction of [Tp′W(CO)₂(NPh)][PF₆] [Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate] with lithium borohydride at -40°C generates Tp′W(CO)(NPh)(CHO) (1), which undergoes hydride migration from carbon to nitrogen (at -70°C, k_obs

Full text of DOI:10.1021/om00040a003

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