139499-27-7Relevant academic research and scientific papers
Stereospecific synthesis of Z olefins bearing an ω-azido group.
Chhen, A.,Vaultier, M.,Carrie, R.
, p. 4953 - 4956 (2007/10/02)
Ylides derived from ω-azidoalkyltriphenylphosphonium salts were generated at low temperature.They are stable at -80 deg C for several hours and react smoothly and stereospecifically with typical aldehydes to form Z-ω-azido olefins which are the precursors of ω-unsaturated primary and secondary amines.
