127611-46-5

Upstream product

• 100-52-7 benzaldehyde 
• 139499-27-7 (4-Azido-butylidene)-triphenyl-λ⁵-phosphane 

Downstream Products

• 127611-51-2 Hexyl-((Z)-5-phenyl-pent-4-enyl)-amine 
• 17734-21-3 5-phenylpentylamine 
• 35840-83-6 (Z)-5-Phenyl-4-penten-1-amine 
• 145314-31-4 2-((Z)-5-Phenyl-pent-4-enyl)-2H-[1,2,3]triazole-4,5-dicarboxylic acid dimethyl ester 
• 145314-29-0 1-((Z)-5-Phenyl-pent-4-enyl)-1H-[1,2,3]triazole-4,5-dicarboxylic acid dimethyl ester 

Relevant academic research and scientific papers

Stereospecific synthesis of Z olefins bearing an ω-azido group.

Ylides derived from ω-azidoalkyltriphenylphosphonium salts were generated at low temperature.They are stable at -80 deg C for several hours and react smoothly and stereospecifically with typical aldehydes to form Z-ω-azido olefins which are the precursors of ω-unsaturated primary and secondary amines.