139507-50-9

Basic information

• Product Name: methyl 2-(methoxy(methyl)amino)-2-oxoacetate
• Synonyms: methyl 2-(methoxy(methyl)amino)-2-oxoacetate
• CAS NO: 139507-50-9
• Molecular Formula: C5H9NO4
• Molecular Weight: 147.12926
• Mol File: 139507-50-9.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: methyl 2-(methoxy(methyl)amino)-2-oxoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(methoxy(methyl)amino)-2-oxoacetate(139507-50-9)
• EPA Substance Registry System: methyl 2-(methoxy(methyl)amino)-2-oxoacetate(139507-50-9)

Safety Data

• Hazardous Substances Data: 139507-50-9(Hazardous Substances Data)

Upstream product

• 5781-53-3 monomethyl oxalyl chloride 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 

Relevant articles and documents

Asymmetric Transfer Hydrogenation of α-Keto Amides; Highly Enantioselective Formation of Malic Acid Diamides and α-Hydroxyamides

The asymmetric transfer hydrogenation (ATH) of α-keto-1,4-diamides using a tethered Ru/TsDPEN catalyst was achieved in high ee. Studies on derivatives identified the structural elements which lead to the highest enantioselectivities in the products. The α-keto-amide reduction products have been converted to a range of synthetically valuable derivatives.

Total synthesis of symbioramide: A flexible approach for the efficient preparation of structural isomers

A concise, enantioselective total synthesis of symbioramide, starting from simple achiral compounds and racemic α-amino-β-keto ester derivatives is reported. This highly flexible strategy allowed the efficient preparation of seven structural isomers of the natural product as well. The synthesis relies on a convergent route that involves the efficient stereoselective reduction of a α-keto-β-yne ester, and the dynamic kinetic resolution of an α-amino-β-keto ester through ruthenium-mediated asymmetric hydrogenation. Copyright

Oxalic acid derivatives, their preparation and plant growth regulators containing them

Oxalylhydroxamic acid derivatives of the formula I where the substituents have the following meanings: X is oxygen or sulfur; R1 is substituted or unsubstituted alkyl, alkenyl or alkynyl; substituted or unsubstituted monocyclic or polycyclic cycloalkyl or cycloalkylmethyl; substituted or unsubstituted phenyl or phenyl-C1 -C4 -alkyl; R2 is hydrogen or alkyl; R3 is substituted or unsubstituted alkyl, alkenyl or alkynyl; substituted or unsubstituted monocyclic or polycyclic cycloalkyl; substituted or unsubstituted phenyl-C1 -C4 -alkyl or phenoxy-C1 -C4 -alkyl; and their agriculturally useful salts; their manufacture; growth-regulating agents containing them; and methods of regulating plant growth.