1395474-07-3Relevant academic research and scientific papers
Palladium-catalyzed intramolecular reductive olefin hydrocarbonation: Benzylic hydrogen serving as a new hydrogen donor
Dong, Xu,Cui, Jie,Song, Jian,Han, Ying,Liu, Qing,Dong, Yunhui,Liu, Hui
, p. 4903 - 4906 (2017/07/11)
A palladium-catalyzed intramolecular hydrocarbonation of unactivated alkenes was achieved, in which toluene is used as a hydrogen donor for the first time. The radical transfer hydrogenation is designed and realized based on the Bond Dissociation Energy (
Palladium-catalyzed atom transfer radical cyclization of unactivated alkyl iodide
Liu, Hui,Qiao, Zongjun,Jiang, Xuefeng
, p. 7274 - 7277 (2012/09/25)
A palladium-catalyzed atom transfer cyclization of unactivated alkyl iodide has been developed. A radical chain mechanism has been proposed for this transformation, which might not involve an alkylpalladium intermediate.
