139609-39-5Relevant academic research and scientific papers
Total synthesis of calicheamicin γ1I. 2. Development of an enantioselective route to (-)-calicheamicinone
Smith,Pitsinos,Hwang,Mizuno,Saimoto,Scarlato,Suzuki,Nicolaou
, p. 7612 - 7624 (2007/10/02)
The first enantioselective total synthesis of (-)-calicheamicinone (3), the naturally occurring antipode of the calicheamicin aglycon, has been achieved. The key elements of the synthesis are as follows: (i) the use of an asymmetric allylboration reaction
