139618-02-3

Basic information

• Product Name: 2-(1'-hydroxy-3'-phenyl-propyl)-3-methyl-3-sulfolene
• Synonyms: 2-(1'-hydroxy-3'-phenyl-propyl)-3-methyl-3-sulfolene
• CAS NO: 139618-02-3
• Molecular Weight: 266.361
• Mol File: 139618-02-3.mol

Chemical Properties

• CAS DataBase Reference: 2-(1'-hydroxy-3'-phenyl-propyl)-3-methyl-3-sulfolene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1'-hydroxy-3'-phenyl-propyl)-3-methyl-3-sulfolene(139618-02-3)
• EPA Substance Registry System: 2-(1'-hydroxy-3'-phenyl-propyl)-3-methyl-3-sulfolene(139618-02-3)

Safety Data

• Hazardous Substances Data: 139618-02-3(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 1193-10-8 3-methyl-2,5-dihydrothiophen-1,1-dioxide 

Downstream Products

• 139618-10-3 (E)-3-hydroxy-5-methyl-1-phenyl-4,6-heptadiene 

Relevant articles and documents

Studies in alkylation of 3-methyl-3-sulfolene and thermolysis of resulting 2-alkyl-3-sulfolenes: Convenient synthesis of 1,2-disubstituted-1,3-dienes

Various 1,2-disubstituted-1,3-dienes have been synthesised through the alkylation of 3-methyl-3-sulfolene (1) followed by thermolysis of the resulting 2-alkyl-3-methyl-3-sulfolene (3,7). The alkylations with bulky iodides, particularly, containing ethylene ketal or phenyl sulfide moiety yield considerable amounts of rearranged 2-alkyl-3-methyl-2-sulfolene (4). The sulfolenes 3, 4 and 7 have been desulfonylated under mild conditions to yield corresponding 1,3-dienes.