1396274-84-2Relevant academic research and scientific papers
Chemiluminescence-promoted oxidation of alkyl enol ethers by NHPI under mild conditions and in the dark
Anderson,Andia, Alexander A.,Woerpel
supporting information, (2021/02/03)
The hydroperoxidation of alkyl enol ethers using N-hydroxyphthalimide and molecular oxygen occurred in the absence of catalyst, initiator, or light. The reaction proceeds through a radical mechanism that is initiated by N-hydroxyphthalimide-promoted autoxidation of the enol ether substrate. The resulting dioxetane products decompose in a chemiluminescent reaction that allows for photochemical activation of N-hydroxyphthalimide in the absence of other light sources.
Cycloalkenyl nonaflates as electrophilic cross-coupling substrates for palladium catalyzed C-N bond forming reactions with enolizable heterocycles under microwave enhanced conditions
Khader, K.K. Abdul,Sajith, Ayyiliath M.,Padusha, M. Syed Ali,Nagaswarupa,Muralidharan
, p. 1294 - 1305 (2014/03/21)
Microwave-mediated, palladium catalyzed C-N bond forming reactions with activated cycloalkenyl nonaflates and enolizable heterocycles using cesium carbonate as a base and a catalytic system employing Pd(OAc)2/ Xantphos or Pd(OAc)2/dp
Tandem nucleophilic addition/fragmentation of vinylogous acyl nonaflates for the synthesis of functionalized alkynes, with new mechanistic insight
Batsomboon, Paratchata,Gold, Brian A.,Alabugin, Igor V.,Dudley, Gregory B.
, p. 1818 - 1824 (2012/08/07)
Vinylogous acyl nonaflates, like the corresponding triflates, are subject to nucleophile-triggered fragmentation as part of a tandem process for generating functionalized alkynes. Advantages to the use of nonaflates in lieu of triflates include cost and s
