139685-55-5Relevant academic research and scientific papers
Enantioselective syntheses of Monomorium minutum ant venom alkaloids: (5R)-2-(5-Hexenyl)-5-nonyl-3,4-dihydro-2H-pyrrole and (2R,5R)-2-(5-Hexenyl)-5-nonpyrrolidine from (S)-pyroglutamic acid
Rosset,Celerier,Lhommet
, p. 7521 - 7524 (1991)
We describe enantioselective syntheses of 2,5-disubstituted pyrroline and pyrrolidine with unsaturated radical, starting from (S)-pyroglutamic acid
Unsymmetrical 2,5-dialkylpyrrolidines via reductive amination of 1,4-diketones
Jones, Tappey H.,Franko, James B.,Blum, Murray S.,Fales
, p. 789 - 792 (2007/10/02)
Reductive amination of 1,4-diketones with sodium cyanoborohydride and ammonium acetate produced 2,5-dialkylpyrrolidines in good yield and permitted inclusion of side chain unsaturation. The compounds were found in ants of the genus Monomorium.
