139686-31-0

Upstream product

• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 1515-80-6 sorbic acid methyl ester 

Downstream Products

• 139622-58-5 (E)-(4R,5S)-5-Acetoxy-4-phenylsulfanyl-hex-2-enoic acid methyl ester 
• 383368-58-9 (4R,5S,2E)-4,5-epoxyhexenoic acid 
• 139622-46-1 (+/-) methyl (4,5)-anti-4-(2',5'-dimethoxyphenyl)-5-hydroxy-(2E)-hexenoate 
• 139622-58-5 (E)-(4S,5R)-5-Acetoxy-4-phenylsulfanyl-hex-2-enoic acid methyl ester 
• 139686-30-9 (4R,5S) methyl (4,5)-anti-5-hydroxy-4-thiophenoxy-(2E)-hexenoate 
• 152377-31-6 (4S,5R) methyl (4,5)-anti-5-hydroxy-4-thiophenoxy-(2E)-hexenoate 

Relevant academic research and scientific papers

Stereoselective synthesis of alkenylated malonic diamide using masked acyl cyanide

A highly stereoselective synthesis of an alkenylated malonic diamide starting from a γ,δ-epoxy-α,β-unsaturated carboxamide was accomplished using the masked acyl cyanide (MAC: the protected hydroxymalonitrile) via palladium-catalyzed regio- and stereoselective carbon-carbon bond formation.

A facile chemoenzymatic route to optically active 4,5-disubstituted-2E-hexenoate derivastives. II

The reaction of (±) methyl 4,5-trans-epoxy-(2E)-hexenoate (1) with nucleophiles having heteroatoms in the presence of BF3 · Et2O gave the 4,5-anti-5-hydroxy-4- and/or 2,5-anti-5-hydroxy-2-substituted products. Among them, the (±)-4,5

A facile chemoenzymatic route to optically active 4,5-disubstituted-2E-hexenoate derivatives. I

The reaction of (±) methyl 4,5-trans-epoxy-2E-hexenoate (2) with aromatic nucleophiles having an electron-donating group in the presence of BF3 · Et2O gave the 4,5-anti-5-hydroxy-4- or/and 2,5-anti-5-hydroxy-2-substituted products. T