139697-54-4Relevant academic research and scientific papers
Access to 1,2-diketones by an unusual radical cascade
Heng, Rama,Zard, Samir Z.
supporting information; experimental part, p. 3296 - 3298 (2011/05/05)
An unusual radical fragmentation of an unstrained cyclohexane structure was observed leading to complex 1,2-diketones.
Lewis Acid Catalysed Michael-type Addition. A New Regio- and Diastereoselective Annulation Method using Methyl Vinyl Ketone
Duhamel, Pierre,Dujardin, Gilles,Hennequin, Laurent,Poirier, Jean-Marie
, p. 387 - 396 (2007/10/02)
A new annulation method is presented, involving a boron trifluoride catalysed Michael addition of trialkylsilyl enol ethers to methyl vinyl ketone (MVK) in the presence of a hydroxylic compound.This methodology allows regiospecific 3-oxobutylation of eith
