13990-72-2

Basic information

• Product Name: Benzene, 1-fluoro-4-(2-propenyloxy)-
• CAS NO: 13990-72-2
• Molecular Formula: C9H9FO
• Molecular Weight: 152.168
• Mol File: 13990-72-2.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Benzene, 1-fluoro-4-(2-propenyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-fluoro-4-(2-propenyloxy)-(13990-72-2)
• EPA Substance Registry System: Benzene, 1-fluoro-4-(2-propenyloxy)-(13990-72-2)

Safety Data

• Hazardous Substances Data: 13990-72-2(Hazardous Substances Data)

Upstream product

• 371-41-5 4-Fluorophenol 
• 371-35-7 sodium 4-fluorophenoxide 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 
• 1072-43-1 propylene sulphide 
• 420-12-2 thirane 

Downstream Products

• 114544-50-2 cis-N-<<5-(4-fluorophenoxy)methyl-2-methyl-3-phenylisoxazolidin-3-yl>methyl>-1H-1,2,4-triazole 
• 13997-72-3 1-allyl-2-hydroxy-5-fluorobenzene 
• 104605-98-3 (2S)-2-[(4-fluorophenoxy)methyl]oxirane 
• 371-41-5 4-Fluorophenol 
• 398-88-9 4-fluoro-2-propylphenol 
• 85461-06-9 1-allyl-2-methoxycarbonylmethoxy-5-fluorobenzene 
• 85461-07-0 1-(2-oxoethyl)-2-methoxycarbonylmethoxy-5-fluorobenzene 
• 95645-92-4 2-<2-<2-(methoxycarbonylmethoxy)-5-fluorophenyl>ethylidene>cyclopentan-1-one 
• 85461-09-2 2-<2-<2-(butoxycarbonylmethoxy)-5-fluorophenyl>ethyl>-2-cyclopenten-1-one 
• 81580-29-2 1-(4-fluoro-phenoxy)-propan-2-one 

Relevant articles and documents

Aromatic polyethers with low polydispersities from chain-growth polycondensation [4]

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Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant

This paper discloses the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(iii) sulfate as the reoxidant. This methodology requires mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(iii) sulphate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcohols all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds.

Enantioselective synthesis of 1-aminoindene derivativesviaasymmetric Br?nsted acid catalysis

We describe a catalytic asymmetric iminium ion cyclization reaction of simple 2-alkenylbenzaldimines using a BINOL-derived chiralN-triflyl phosphoramide. The corresponding 1-aminoindenes and tetracyclic 1-aminoindanes are formed in good yields and high enantioselectivities. Further, the chemical utility of the obtained enantiopure 1-aminoindene is demonstrated for the asymmetric synthesis of (S)-rasagiline.

Chemoselective Epoxidation of Allyloxybenzene by Hydrogen Peroxide Over MFI-Type Titanosilicate

The chemoselective synthesis of 2-(phenoxymethyl)oxirane from allyloxybenzene is achieved with over 90 % yield in a sustainable reaction system using titanium-substituted silicalite-1 (TS-1) as a catalyst, hydrogen peroxide (H2O2) as an oxidant, and a mixture of MeOH/MeCN as a solvent at 40 °C. No acid-catalyzed side reactions prompted by the Lewis acidity of the Ti active site in TS-1 are observed. The TS-1 catalyst can also promote the formation of oxiranes from various p-substituted allyloxybenzenes in good yields. The reaction mechanism is investigated through the reaction with other allyloxy compounds. The results, which are supported by DFT calculations, indicate that an active species of Ti peroxides formed from the reaction of TS-1 with H2O2 selectively oxidizes the allyloxybenzene to 2-(phenoxymethyl)oxirane.