139913-06-7

Basic information

• Product Name: {(η6-C6Me6)(PMe3)ClRu(PPh2CCH)}(PF6)
• CAS NO: 139913-06-7
• Molecular Weight: 730.055
• Mol File: 139913-06-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(η6-C6Me6)(PMe3)ClRu(PPh2CCH)}(PF6)(CAS DataBase Reference)
• NIST Chemistry Reference: {(η6-C6Me6)(PMe3)ClRu(PPh2CCH)}(PF6)(139913-06-7)
• EPA Substance Registry System: {(η6-C6Me6)(PMe3)ClRu(PPh2CCH)}(PF6)(139913-06-7)

Safety Data

• Hazardous Substances Data: 139913-06-7(Hazardous Substances Data)

Upstream product

• 80298-82-4 (η(6)-hexamethylbenzene)dichloro(PMe3)ruthenium(II) 
• 6104-47-8 ethynyldiphenylphosphine 

Relevant articles and documents

A novel bifunctional bridging phosphinomethylalkoxycarbene ligand from (diphenylpshosphinoacetylene)ruthenium complexes

Some new neutral and cationic C(Ph2)P>(η6-arene)ruthenium(II) complexes have been prepared, namely (η6-arene)Cl2RuP(Ph2)CCH and 6-arene)(L)ClRuP(Ph2)CCH>+ (L = PMe3, SMe2).Activation of the terminal alkyne function allowed formation of unsymmetrical dinuclear derivatives in a process involving formation of a bridging phosphino-methoxycarbene ligand.