A novel bifunctional bridging phosphinomethylalkoxycarbene ligand from (diphenylpshosphinoacetylene)ruthenium complexes

DOI: 10.1016/0022-328X(92)85008-K

Source and publish data:

Journal of Organometallic Chemistry p. 65 - 70 (1992)

Update date:2022-08-04

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Authors:

Gaye, Mohamed

Demerseman, Bernard

Dixneuf, Pierre H.

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Article abstract of DOI:10.1016/0022-328X(92)85008-K

Some new neutral and cationic C(Ph2)P>(η⁶-arene)ruthenium(II) complexes have been prepared, namely (η⁶-arene)Cl2RuP(Ph2)C<*>CH and <(η⁶-arene)(L)ClRuP(Ph2)C<*>CH>⁺ (L = PMe3, SMe2).Activation of the terminal alkyne function allowed formation of unsymmetrical dinuclear derivatives in a process involving formation of a bridging phosphino-methoxycarbene ligand.

Full text of DOI:10.1016/0022-328X(92)85008-K

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Product name:{(η6-C6Me6)(PMe3)ClRu(PPh2CCH)}(PF6)

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