139934-44-4Relevant academic research and scientific papers
Structure, derivatisation, and metal complexation of p-cyclohexylcalix[4]arene
Fong, Isabella,Massi, Massimiliano,Mocerino, Mauro,Ogden, Mark I.,Phe, Rene Z. H.,Shen, Chao,Sobolev, Alexandre N.
, (2021/08/13)
Driven by an interest in the impact of the para-substituent of calix[4]arenes on metal complexation and structural chemistry, studies of p-cyclohexylcalix[4]arene (L) have been carried out. The 1:1 dichloromethane and dimethylformamide solvates were found
Extension of the hydrophobic cavity of calix[4]arene by 'upper rim' functionalization
Arduini,Pochini,Rizzi,Sicuri,Ugozzoli,Ungaro
, p. 905 - 912 (2007/10/21)
The hydrophobic cavity of calix[4]arene (1) has been extended by 'upper rim' functionalization with different alkyl groups. Using p-chloromethylcalix[4]arene (2) as the intermediate, the synthesis of ethyl (4) and p-benzylcalix[4]arenes (5 a-c) was performed. By reaction of 1 with cyclohexene p-cyclohexylcalix[4]arene (6) was obtained. The crystal structure of p-ethylcalix[4]arene (4) was solved.
