13998-69-1Relevant academic research and scientific papers
NUCLEOPHILIC SUBSTITUTION AT NITROGEN-CENTERED RADICALS: REACTIONS OF DIPHENYLPHOSOPHIDE IONS WITH N,N-DIBUTYL-p-TOLUENESULFONAMIDE BY THE SRN1 MECHANISM
Foray, Gabriela S.,Penenory, Alicia B.,Rossi, Roberto A.
, p. 356 - 358 (1995)
The photostimulated reaction of N,N-dibutyl-p-toluenesulfonamide with diphenylphosphide ions in liquid ammonia leads to the corresponding phosphinic amides after oxidation.Inhibition experiments with p-dinitrobenzene and 2,2,6,6-tetramethyl-1-piperidinylo
Easily Prepared Mono(N,N-dialkylamino)phosphine Palladium(II) Complexes: Structural and Catalytic Evaluation
Adeyinka, Adedapo S.,Holzapfel, Cedric W.,Lamola, Jairus L.,Maumela, Munaka C.,Mmutlane, Edwin M.,Ngodwana, Lonwabo,Shilubana, Joy C.,Vatsha, Banele
supporting information, p. 2578 - 2582 (2021/07/06)
The search for efficient, active and universal catalyst systems for transition-metal catalyzed cross-coupling reactions, continues to be of interest to researchers world-wide. Herein, we report two new Pd(II) complexes, effortlessly prepared from N,N-dialkylamino-phosphines for Suzuki-Miyaura cross-coupling reactions. These sufficiently hindered (% VBur=30.0–31.5 %) and electron rich (vCO=1947.41–1946.29 cm?1) aminophosphines formed active catalysts for Suzuki-Miyaura coupling of aryl bromides and chlorides.
Organic phosphorus compounds 106.1 a 31P-NMR study of phosphinous-, phosphinic-, and thiophosphinic amides
Maier, Ludwig,Diel, Peter J.
, p. 273 - 300 (2007/10/03)
The synthesis, physical, chemical and spectroscopic properties of eight different types of phosphinous-, phosphinic-and thiophosphinic amides are reported. It is shown that the 31P-chem. shifts of tertiary amides are at lower magnetic field than that of secondary amides. As an exception, in the bis(tertiary butyl) series this trend is reversed.
