NUCLEOPHILIC SUBSTITUTION AT NITROGEN-CENTERED RADICALS: REACTIONS OF DIPHENYLPHOSOPHIDE IONS WITH N,N-DIBUTYL-p-TOLUENESULFONAMIDE BY THE SRN1 MECHANISM

Article abstract of DOI:10.1002/poc.610080507

The photostimulated reaction of N,N-dibutyl-p-toluenesulfonamide with diphenylphosphide ions in liquid ammonia leads to the corresponding phosphinic amides after oxidation.Inhibition experiments with p-dinitrobenzene and 2,2,6,6-tetramethyl-1-piperidinylo