1400655-82-4Relevant academic research and scientific papers
Mild rhodium(III)-catalyzed C-H activation and intermolecular annulation with allenes
Wang, Honggen,Glorius, Frank
supporting information; experimental part, p. 7318 - 7322 (2012/09/08)
All(enes) great! A novel RhIII-catalyzed oxidative coupling with allenes under mild conditions provides heterocycles with exocyclic double bonds. This reaction features low catalyst loadings, high regio- and stereoselectivity, and excellent substrate scope. The products were derivatized and preliminary mechanistic studies were conducted. Copyright
