1400790-34-2Relevant academic research and scientific papers
Carbon disulfide binding at dinuclear and mononuclear nickel complexes ligated by a redox-active ligand: Iminopyridine serving as an accumulator of redox equivalents for the activation of heteroallenes
Bheemaraju, Amarnath,Beattie, Jeffrey W.,Lord, Richard L.,Martin, Philip D.,Groysman, Stanislav
, p. 9595 - 9597 (2012)
The dinuclear complex Ni2L1(η2-CS 2)2 (2), featuring iminopyridine ligation, is prepared by COD substitution from Ni2L1(COD)2 (1). Spectroscopic, structural, and theoretical data reveals significant activation of the metal-bound C-S bonds, as well as the different oxidation states of the iminopyridine in 1 (1-) and 2 (0).
