140145-93-3

Upstream product

• 139926-50-4 (5R*,6S*)-5-methyl-6-phenyl-6-triethylsilyloxy-hex-3-en-2-one 
• 74-88-4 methyl iodide 
• 139926-50-4 (5S*,6S*)-5-methyl-6-phenyl-6-triethylsilyloxyhex-3-en-2-one 

Downstream Products

• 139926-65-1 (2S*,3S*,4R*,5S*,6S*)-2,3,4,5-tetranethyl-6-phenyltetrahydropyran-2-ol 
• 139926-65-1 (2S*,3R*,4S*,5R*,6S*)-2,3,4,5-tetranethyl-6-phenyltetrahydropyran-2-ol 

Relevant academic research and scientific papers

Conjugate addition of organocuprates to γ-methyl-δ-oxy-α,β-enones. Influence of the alkoxy substituent on the diastereoselection

The stereochemistry of the conjugate addition of cuprates to the title compounds is mainly governed by the γ-methyl group, but the alkoxy substituent also plays a role.