Conjugate addition of organocuprates to γ-methyl-δ-oxy-α,β-enones. Influence of the alkoxy substituent on the diastereoselection

DOI: 10.1016/0022-328X(92)83121-W

Source and publish data:

Journal of Organometallic Chemistry p. 281 - 305 (1992)

Update date:2022-08-04

Topics:

Authors:

Courtemanche, Gilles

Alexakis, Alexandre

Vaissermann, Jacqueline

Normant, Jean-F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(92)83121-W

The stereochemistry of the conjugate addition of cuprates to the title compounds is mainly governed by the γ-methyl group, but the alkoxy substituent also plays a role.

Full text of DOI:10.1016/0022-328X(92)83121-W

Products guided by the article

Product name:(3R*,4S*,5R*,6S*)-3,4,5-trimethyl-6-phenyl-6-triethylsilyloxyhexan-2-one

Cas No:140145-93-3

R&D Labs maybe for 140145-93-3

Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Zibo Xiaoguang Chemical Material Co., Ltd

Contact:15954099116

Address:Boshan Development Zone
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Taizhou Elitechemie MediPharma Technology Co.,Ltd.

Contact:+86-523-86810021

Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
JiYi Chemical (Beijing) Co., Ltd.

Contact:+86-10-89385733

Address:Shilou Town of Fangshan District， Beijing

Relevant to this article

Facile synthesis of 3,6-disubstituted-1,2,4-triazolo-[3,4-b]-1,3,4- thiadiazoles via oxidative cyclization of n-heteroaryl-substituted hydrazones and their biological activity

Doi:10.1002/jhet.870
(2012)
Continuous-flow hydrogenation of carbon dioxide to pure formic acid using an integrated scCO₂ process with immobilized catalyst and base

Doi:10.1002/anie.201203185
(2012)
Synthesis of heterodinuclear hemisalen complexes on a hexaarylbenzene scaffold and their application for the cross-pinacol coupling reaction

Doi:10.1002/chem.201303946
(2014)
Synthesis and characterizations of bismuth-bridged triiridium carbonyl complexes containing germyl/germylene and stannyl/stannylene ligands

Doi:10.1021/om300813t
(2012)
Synthesis and bioevaluation of novel arylnaphthalene lignans as anticancer agents

Doi:10.1007/s00044-012-0245-1
(2013)
Synthesis and evaluation of tripeptidic plasmin inhibitors with nitrile as warhead

Doi:10.1002/psc.2442
(2012)

Article Doi