1401464-92-3

Basic information

• Product Name: 2-{(2-cyclohepta-2,4,6-trienyl)-1-[4-(trimethylsilylethynyl)phenyl]ethylidene}malononitrile
• Synonyms: 2-{(2-cyclohepta-2,4,6-trienyl)-1-[4-(trimethylsilylethynyl)phenyl]ethylidene}malononitrile
• CAS NO: 1401464-92-3
• Molecular Weight: 354.527
• Mol File: 1401464-92-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-{(2-cyclohepta-2,4,6-trienyl)-1-[4-(trimethylsilylethynyl)phenyl]ethylidene}malononitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 2-{(2-cyclohepta-2,4,6-trienyl)-1-[4-(trimethylsilylethynyl)phenyl]ethylidene}malononitrile(1401464-92-3)
• EPA Substance Registry System: 2-{(2-cyclohepta-2,4,6-trienyl)-1-[4-(trimethylsilylethynyl)phenyl]ethylidene}malononitrile(1401464-92-3)

Safety Data

• Hazardous Substances Data: 1401464-92-3(Hazardous Substances Data)

Upstream product

• 75883-03-3 4'-(2-trimethylsilylethynyl)acetophenone 
• 1401464-91-2 2-(1-(4-((trimethylsilyl)ethynyl)phenyl)ethylidene)malononitrile 
• 27081-10-3 tropylium tetrafluoroborate 

Downstream Products

• 1401464-90-1 2-(4-ethynylphenyl)-1,8a-dihydroazulene-1,1-dicarbonitrile 
• 1401464-93-4 2-[(4-(trimethylsilylethynyl)phenyl)]-1,8a-dihydroazulene-1,1-dicarbonitrile 
• 1401464-96-7 2-(4'-bromoethynylphenyl)-1,8a-dihydroazulene-1,1-dicarbonitrile 
• 1401464-94-5 C₂₀H₁₁AgN₂ 

Relevant articles and documents

Dihydroazulene-buckminsterfullerene conjugates

The dihydroazulene (DHA)/vinylheptafulvene (VHF) photo/thermoswitch has recently attracted interest as a molecular switch for molecular electronics. In this field, Buckminsterfullerene, C60, has been shown to be a useful anchoring group for adhering a molecular wire to an electrode. Here we have combined the two units with the overall aim to elucidate how C60 influences the DHA-VHF switching events. Efficient synthetic protocols for making covalently linked DHA-C60 conjugates were developed, using Prato, Sonogashira, Hay, and Cadiot-Chodkiewicz reactions. These syntheses provide as well a variety of potentially useful DHA and C60 building blocks for acetylenic scaffolding. The two units were separated by bridges of various lengths, such as oligo(phenyleneethynylene) (OPE2 and OPE3) wires. The distance of separation was found to influence strongly the light-induced ring-opening reaction of DHA to its corresponding VHF. Thus, C60 was found to significantly quench this conversion when situated closely to the DHA unit.