140150-02-3

Upstream product

• 100-52-7 benzaldehyde 
• 140149-89-9 3-Bromo-3-(trimethylsilyl)-2-phenyl-1-propene 
• 98-83-9 isopropenylbenzene 
• 104516-09-8 1-phenylbuta-2,3-dien-1-ol 
• 733-53-9 p-methoxyphenyl(phenyl)iodonium tetrafluoroborate 

Relevant academic research and scientific papers

Palladium-catalyzed arylation of α-allenic alcohols with hypervalent iodonium salts: Synthesis of epoxides and diol cyclic carbonates

Pd(0)-catalyzed arylation of the aryl-substituted α-allenic alcohols with hypervalent iodonium salts afforded substituted trans-epoxides. Alternatively, arylation of the alkyl-substituted α-allenic alcohols in the presence of K2CO3 a

Sulfur-mediated allylic C-H arylation, epoxidation, and aziridination

Transition-metal-free, sulfur-mediated allylic C-H arylation, epoxidation, and aziridination were realized through one-pot procedures. The reaction design involved initial addition between olefins and triflic anhydride activated sulfoxides, followed by subsequent reactions of the allylic sulfur ylides generated under basic conditions with arylboronic acids, aldehydes, or aldimines, to give allylic arylation, epoxidation, or aziridination products, respectively.